Ordinary ABS sheets are thermoplastic engineering plastics made from acrylonitrile (A), butadiene (B), and styrene (S) ternary copolymers. The double bonds in the butadiene molecular structure give it a certain degree of toughness, but it has not undergone flame-retardant modification and is therefore a flammable material.
Flame-retardant ABS sheets, on the other hand, are functional plastics made by adding flame retardants (such as phosphorus-based, nitrogen-based, and halogen-free flame retardants) to ordinary ABS, significantly improving its fire resistance. Its core objective is to meet higher fire safety requirements while retaining the original mechanical and processing properties of ABS.
1. Flame Retardant Performance: A Fundamental Leap from "Flammable" to "Flammable Resistant"
Ordinary ABS sheets have extremely poor flame retardant performance, with an oxygen index of only 18%-20%, belonging to the UL94 HB level (slow burning, no self-extinguishing). They easily continue to burn when exposed to an open flame, releasing large amounts of black smoke and toxic gases during combustion.
Flame-retardant ABS sheets, through flame-retardant modification, have an oxygen index exceeding 25%, achieving UL94 V-0 level (self-extinguishing time ≤ 5 seconds for vertical burning at a thickness of 1.6mm) and even 5VA level (the highest flame retardant rating). During combustion, the flame retardant forms a dense char layer, isolating oxygen and heat transfer, effectively inhibiting flame spread, and significantly reducing smoke density (SDR), decreasing toxic gas release by approximately 30%.
2. Safety and Environmental Protection: An Improvement from "Toxic Combustion" to "Low Smoke and Non-Toxic"
When ordinary ABS sheets burn, the decomposition of butadiene produces large amounts of black smoke and toxic gases, posing a significant threat to human health and fire rescue operations.
Flame-retardant ABS sheets (especially halogen-free flame-retardant systems) produce safer combustion products:
Smoke density: lower, reducing the risk of smoke asphyxiation in fires;
Toxic gases: carbon monoxide generation <0.3%, and no halogen release (avoiding the strong corrosiveness of traditional halogenated flame retardants);
Environmental compliance: meets international environmental standards, suitable for environmentally sensitive applications such as electronics, electrical appliances, and medical equipment.
3. Physical and Mechanical Properties: Balancing Flame Retardancy and Practicality
The addition of flame retardants will have some impact on the original properties of ABS, but through modification techniques, a balance between flame retardancy and performance can be achieved:
Density: The density of ordinary ABS is slightly lower than that of flame-retardant ABS due to the addition of flame retardants;
Heat Deflection Temperature: The heat deflection temperature (HDT) of ordinary ABS is approximately above 100℃, while that of flame-retardant ABS is reduced to 75-90℃ due to the influence of flame retardants (but still meets the requirements for most room temperature applications);
Impact Resistance: The notched impact strength of ordinary ABS is approximately 10-15 KJ/m², while flame-retardant ABS, through the use of macromolecular phosphorus-based flame retardants, can maintain an impact strength retention rate of ≥80%, even better than that of ordinary ABS;
Processing Performance: The processing temperature of flame-retardant ABS is close to that of ordinary ABS (200-240℃), but attention must be paid to the screw speed to avoid decomposition of the flame retardant (such as phosphorus-based flame retardants).